The mutarotation of glucose is first order in glucose concentra... | Filo
The mutarotation of glucose is first order in glucose concentra... | Filo
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The equilibrium constant for the mutarotation, α-D-glucose ⇌β-D glucose is 1.8 . What per cent of the α-form remains under equilibrium? (a) 35.7 (b) 64.3 (c) 55.6 (d) 44.4 | Numerade
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The mutarotation of glucose is catalyzed by acids and bases and is first order in the concentration of glucose. When perchloric acid is used as a catalyst, the concentration of hydrogen ions may be taken to be equal to the concentration of perchloric acid, and the catalysis by perchlorate ion may be ignored since it is such a weak base. The following first-order constants were obtained at 18^∘ C [HClO4] / molL^-1 0.0010 0.0048 0.0099 k / 10^-4min^-1 1.25 1.38 1.53
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