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Overcoming the 'fluoro wall'—researchers observe tunneling effect of heavy atoms for the first timebut which was considered virtually impossible for the relatively heavy fluorine atom. The researchers were able to prove that even fluorine atoms can effectively tunnel—i.e., make a molecule ...
Herbert Roesky relates how the small, highly electronegative fluorine atom unveiled the chemical reactivity of noble gases and found many practical applications. but it can also render organic ...
With the aid of quantum chemical simulations they were able to prove for the first time that heavy fluorine atoms can also ...
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